Trimethylaluminum: Bonding by Charge and Current Topology.
Bielefeld, Germany. In Angew Chem Int Ed Engl, Dec 2015
The data can be interpreted as Al2 Me6 being predominantly ionically bonded, with clear indications of topological asymmetry for the bridging AlC bonds owing to delocalized multicenter bonding.
Ligand field influence on the electronic and magnetic properties of quasi-linear two-coordinate iron(II) complexes.
Manchester, United Kingdom. In Dalton Trans, Jul 2015
Ab initio calculations of the CASSCF/RASSI/SINGLE-ANISO type have indicated that the orbital energies of the complexes, as well as those of Fe(Ar(Me6))2, 4, where Ar(Me6) is C6H3-2,6(C6H2-2,4,6-Me3)2), are in the order d(xy)≈ d(x(2)-y(2)) < d(xz) ≈ d(yz) < d(z(2)), and the iron(II) complexes in this ligand field have the (d(xy), d(x(2)-y(2)))(3)(d(xz), d(yz))(2)(d(z(2)))(1) ground electronic configuration with a substantial orbital contribution to their effective magnetic moments.
Syntheses of Mononuclear and Dinuclear Aluminum Complexes Stabilized by Phenolato Ligands and Their Applications in the Polymerization of ε-Caprolactone: A Comparative Study.
Suzhou, China. In Inorg Chem, Jun 2015
In order to compare the catalytic activities of these bimetallic complexes with their mononuclear counterparts, mono(phenolato) aluminum complexes AlMe2[ON](1) (7), AlMe2[ON](2) (8), AlMe2[ON](3) (9), AlEt2[ON](2) (10), and AlEt2[ON](3) (11) were synthesized from reactions of 1 equiv of AlMe3 or 2 equiv of AlEt3 with phenols that bear piperidine moieties, i.e., [2-(CH2NC5H10)-4,6-Me2-C6H2OH (H[NO](1)), 2-(CH2NC5H10)-4-Me-6-(t)Bu-C6H2OH (H[NO](2)), and 2-(CH2NC5H10)-4,6-(t)Bu2-C6H2OH (H[NO](3))], respectively.
Reaction of a germylene, stannylene, or plumbylene with trimethylaluminum and trimethylgallium: insertion into Al-C or ga-C bonds, a reversible metal-carbon insertion equilibrium, and a new route to diplumbenes.
Davis, United States. In Inorg Chem, Mar 2015
The reaction of the tetrylenes Ge(Ar((Me)6))2, Sn(Ar((Me)6))2, and Pb(Ar((Me)6))2 [Ar((Me)6) = C6H3-2,6-(C6H2-2,4,6-(CH3)3)2] with the group 13 metal alkyls trimethylaluminum and trimethylgallium afforded (Ar((Me)6))2Ge(Me)AlMe2 (1), (Ar((Me)6))2Ge(Me)GaMe2 (2), and (Ar(Me6))2Sn(Me)GaMe2 (3) in good yields via insertion reaction routes.
International Union of Basic and Clinical Pharmacology. XCIV. Adhesion G protein-coupled receptors.
Amsterdam, Netherlands. In Pharmacol Rev, 2014
The new names, with old and alternative names within parentheses, are: ADGRA1 (GPR123), ADGRA2 (GPR124), ADGRA3 (GPR125), ADGRB1 (BAI1), ADGRB2 (BAI2), ADGRB3 (BAI3), ADGRC1 (CELSR1), ADGRC2 (CELSR2), ADGRC3 (CELSR3), ADGRD1 (GPR133), ADGRD2 (GPR144), ADGRE1 (EMR1, F4/80), ADGRE2 (EMR2), ADGRE3 (EMR3), ADGRE4 (EMR4), ADGRE5 (CD97), ADGRF1 (GPR110), ADGRF2 (GPR111), ADGRF3 (GPR113), ADGRF4 (GPR115), ADGRF5 (GPR116, Ig-Hepta), ADGRG1 (GPR56), ADGRG2 (GPR64, HE6), ADGRG3 (GPR97), ADGRG4 (GPR112), ADGRG5 (GPR114), ADGRG6 (GPR126), ADGRG7 (GPR128), ADGRL1 (latrophilin-1, CIRL-1, CL1), ADGRL2 (latrophilin-2, CIRL-2, CL2), ADGRL3 (latrophilin-3, CIRL-3, CL3), ADGRL4 (ELTD1, ETL), and ADGRV1 (VLGR1, GPR98).
Adhesion-GPCRs in the male reproductive tract.
Oxford, United Kingdom. In Adv Exp Med Biol, 2009
Gpr64 is the best characterised of the adhesion-GPCRs in the male reproductive system and the phenotype of Gpr64 knock-out mice implicates this receptor in the regulation of fluid absorption in the efferent ducts and proximal epididymis.
Runx2 regulates G protein-coupled signaling pathways to control growth of osteoblast progenitors.
Worcester, United States. In J Biol Chem, 2008
Affymetrix expression profiling shows that the C terminus of Runx2 regulates genes involved in G protein-coupled receptor signaling Rgs2, Rgs4, Rgs5, Rgs16, Gpr23, Gpr30, Gpr54, Gpr64, and Gna13.