The interaction of Mozobil(™) with carboxylates.
Pavia, Italy. In Org Biomol Chem, Feb 2016
(1)H NMR titration experiments have shown that in the 7-10 pH interval, LH3(3+), LH2(2+) and LH(+) forms establish π-π interactions with diphenyl-4,4'-dicarboxylate, according to a topological arrangement which excludes the formation of H-bonds.
Pentanuclear [2.2] spirocyclic lanthanide(iii) complexes: slow magnetic relaxation of the Dy(III) analogue.
Kānpur, India. In Dalton Trans, Dec 2015
The reaction of LnCl3·6H2O (Ln = Dy(3+), Tb(3+) and Ho(3+)) with the multisite coordinating ligand N'-(2-hydroxy-3-(hydroxymethyl)-5-methylbenzylidene)acetohydrazide (LH3) in the presence of pivalic acid (PivH) leads to the formation of three isostructural homometallic pentanuclear complexes, [Dy5(LH)4(η(1)-Piv)(η(2)-Piv)3(μ2-η(2)η(1)Piv)2(H2O)]·Cl·9·5H2O·5MeOH (1), [Tb5(LH)4(η(1)-Piv)(η(2)-Piv)3(μ2-η(2)η(1)Piv)2(H2O)]·Cl·10.5H2O·2MeOH·2CHCl3
Decanuclear Ln10 Wheels and Vertex-Shared Spirocyclic Ln5 Cores: Synthesis, Structure, SMM Behavior, and MCE Properties.
Bhubaneshwar, India. In Chemistry, Dec 2015
The reaction of a Schiff base ligand (LH3 ) with lanthanide salts, pivalic acid and triethylamine in 1:1:1:3 and 4:5:8:20 stoichiometric ratios results in the formation of decanuclear Ln10 (Ln=Dy(1), Tb(2), and Gd (3)) and pentanuclear Ln5 complexes (Ln=Gd (4), Tb (5), and Dy (6)), respectively.
Lysyl hydroxylase 3 is secreted from cells by two pathways.
Oulu, Finland. In J Cell Physiol, 2012
LH3 molecules found in the cell medium are secreted through the Golgi complex, and the secretion is dependent on LH3 glycosyltransferase activity; LH3 found on the cell surface bypasses the Golgi complex